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Introduction to NMR v2.0
Source PCCAL, University of Nottingham
ISBN: 1 84211 010 0
Versions Available Internet
Programmer Joe Cutting
Subject Specialists Saul Tendler and Phil Williams
Summary

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Contents
1: Introduction to NMR
The activity begins with a general description of how NMR works. It then moves on to the idea of sets of protons being "equivalent" and a discussion of the features to look for when interpreting NMR spectra. Finally there is an in depth description of the use of delta values and how they are derived.
2: Interpreting NMR Spectra
This activity concentrates on the various features of a molecule's structure which may affect its NMR spectra. This includes:
  • The effect of double bonds on equivalence sets.
  • Shielding and deshielding.
  • Pi electrons.
There is also a discussion of proton counting and significance of the area of spectra peaks. The activity finishes with the resonance positions of some common molecule fragments.
3: Coupling
This activity starts with an introduction to the concept of spin-spin coupling with an emphasis on the effect that this has on NMR spectra. The activity then discusses coupling constants and the conditions necessary for protons to couple. Finally the activity covers heteronuclear NMR with a discussion of the practical problems of Carbon 13 NMR and the use of proton decoupling.